Production of polyconjugated polymer systems in the dehydrogenation of polyacenaphthylene

descriptionPublicationkeyboard_double_arrow_right Article 01 Mar 1970 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 19, pages 557-561 (issn: 0568-5230, eissn: 1573-9171,

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Authors: I. F. Gavrilenko; N. N. Stefanovskaya; M. P. Teterina; N. A. Shimanko; E. I. Tinyakova; B. A. Dolgoplosk;

doi: 10.1007/bf00848979

Production of polyconjugated polymer systems in the dehydrogenation of polyacenaphthylene

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Abstract

1. The kinetics of the dehydrogenation of polyacenaphthylene by chloranil in chlorobenzene solution at 160–200° was studied. 2. The structural transformations occurring during the process of dehydrogenation of polyacenaphthylene were characterized by the methods of IR and UV spectroscopy. 3. Dehydrogenated polyacenaphthylene retains its solubility in hydrocarbons. The content of paramagnetic particles reaches 3.7·1018 per g of the polymer, the electric conductivity (0.17–0.75)·10−12 cm−1 ·sec−1.

Related Organizations

Russian Academy of Sciences
Russian Federation
A.V.Topchiev Institute of Petrochemical Synthesis
Russian Federation

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