Aliphatic fluoro diazo compounds Communication 2. Perfluoro(?-diazo ketones)

descriptionPublicationkeyboard_double_arrow_right Article 01 Jun 1965 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences, USSR Division of Chemical Science, volume 14, pages 996-999 (issn: 0568-5230, eissn: 1573-9171,

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Authors: B. L. Dyatkin; E. P. Mochalina;

doi: 10.1007/bf00845743

Aliphatic fluoro diazo compounds Communication 2. Perfluoro(?-diazo ketones)

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Abstract

1. By the action of 2-diazo-1,1,1-trifluoroethane on perfluoro carboxylic anhydrides a number of perfluoro(α-diazo ketones) were obtained. 2. With the case of 3-diazohexafluoro-2-butanone as example, some chemical properties of perfluoro(α-diazo ketones) were investigated. The pyrolysis of 3-diazohexafluoro-2-butanone is accompanied by Wolff rearrangement and leads to bistrifluoromethylketene.

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Russian Academy of Sciences
Russian Federation

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