
doi: 10.1007/bf00772975
handle: 2381/19867
It is well known [1-4] that the rate constants of different elementary reactions are often interdependent. Relationships determined by the principle of detailed balancing exist between them [1-5] when microreversibility is valid and by the generalizations of that principle [5-8] when it is not (for example, in magnetic fields, during macroscopic rotations, etc.). Nevertheless, in practice the verification of consistency in the kinetic constants for complicated transformation schemes involves a certain amount of technical difficulty.
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