
doi: 10.1007/bf00772472
1. We designed an apparatus and method of determining the phase composition at nitriding temperature. 2. At the beginning of the nitriding process (0.5 h) all phases corresponding to the Fe−N phase diagram are observed in Armco iron and the steels tested. With increasing holding times at nitriding temperature there are no changes in the phase composition but the distortion of the crystal lattice, manifest in line broadening, increases. 3. The periodicity of changes in the stress and hardness of the nitrided case in the process of formation was established, and therefore the results of nitriding may also depend on the time at which it ceases.
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