Mechanism of hydrocracking n-paraffins on nickel silicate

descriptionPublicationkeyboard_double_arrow_right Article 01 Dec 1984 English Publisher:Springer Science and Business Media LLCJournal:Chemistry and Technology of Fuels and Oils, volume 20, pages 599-600 (issn: 0009-3092, eissn: 1573-8310,

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Authors: S. A. Sergienko; G. D. Chukin;

doi: 10.1007/bf00726433

Mechanism of hydrocracking n-paraffins on nickel silicate

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Abstract

In order to determine the role of the metal and the acidic center in paraffin hydrocracking on reduced nickel silicate, the authors investigated the effects of catalytic poisons that selectively poison the L-centers (piperdine) and the metallic nickel (thiophene) on the rates of cleavage of n-dodecane and hydrogenation of 0-xylene. IR spectroscopy was used to monitor the interaction of the catalytic poisons with the surface of the reduced nickel silicate. The results of this research are described in this article.

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