Living carbocationic polymerization

descriptionPublicationkeyboard_double_arrow_right Article 01 Dec 1989 English Publisher:Springer Science and Business Media LLCJournal:Polymer Bulletin, volume 22, pages 463-470 (issn: 0170-0839, eissn: 1436-2449,

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Authors: C. Charles Chen; Gabor Kaszas; Judit E. Puskas; Joseph P. Kennedy;

doi: 10.1007/bf00718920

Living carbocationic polymerization

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Abstract

La polymerisation de l'isobutene dans CH 3 Cl amorcee par BCl 3 en presence de DMSO ou de DMA donne, en fonction de l'alcool tertiaire utilise, des PIB telecheliques tCl-PIB-tCl lineaires ou en etoile a 3 branches terminees par des chloropropyl tertiaires (tCl). L'etude du mecanisme montre que les chlorures tertiaires formes par reaction de BCl 3 avec les alcools, seraient les amorceurs

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