Synthesis and properties of ansa-titano- and ansa-zirconocenes

descriptionPublicationkeyboard_double_arrow_right Article 01 May 1993 English Publisher:Springer Science and Business Media LLCJournal:Russian Chemical Bulletin, volume 42, pages 928-931 (issn: 1066-5285, eissn: 1573-9171,

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Authors: A. V. Churakov; I. E. Nifant'ev; I. F. Urazovskii; G. I. Nikonov; D. S. Yufit; Yu. T. Struchkov;

doi: 10.1007/bf00698963

Synthesis and properties of ansa-titano- and ansa-zirconocenes

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Abstract

A series of methyl and allyl derivatives of ansa-titano- and ansa-zirconocenes with isopropylidene or dimethylsilyl bridging groups were synthesized. A dinuclear complex, [Me2C(C5H4)2]2Ti2O2, resulting from the thermal decomposition of the corresponding dimethyl derivative of ansa-titanocene in the air, was characterized by X-ray diffraction analysis.

Related Organizations

Russian Academy of Sciences
Russian Federation
Lomonosov Moscow State University
Russian Federation
A. N. Nesmeyanov Institute of Organoelement Compounds
Russian Federation

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