DSC non-isothermal crystallization curves in polyoxymethylene

descriptionPublicationkeyboard_double_arrow_right Article 01 Mar 1995 English Publisher:Springer Science and Business Media LLCJournal:Colloid & Polymer Science, volume 273, pages 227-232 (issn: 0303-402X, eissn: 1435-1536,

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Authors: C. J. G. Plummer; H. -H. Kausch;

doi: 10.1007/bf00657828

DSC non-isothermal crystallization curves in polyoxymethylene

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Abstract

Non-isothermal crystallization curves by differential scanning calorimetry for two-dimensional spherulite growth in polyoxymethylene have been modeled using the Avrami equation, taking into account heat dissipation in the sample holder during the phase transition. Good agreement is found for scanning rates up to 40 Kmin−1 between experimental curves and predictions based on a knowledge of the isothermal crystallization kinetics of the same samples.

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École Polytechnique Fédérale de Lausanne EPFL
Switzerland

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