Dinuclear complexes with a ?-cyano ligand. Part XI(1). Synthesis and characterization of several derivatives ofcis-[Co(NH3)(en)2(H2O)]3+
Copyright policy )Dinuclear complexes with a ?-cyano ligand. Part XI(1). Synthesis and characterization of several derivatives ofcis-[Co(NH3)(en)2(H2O)]3+
The new complex double saltscw-[Co(NH3)(en)2(H2O)]2 [M(CN)4]3 (en = ethylenediamine; M = Ni, Pd or Pt),cis-[Co(NH3(en)2(H2O)]2[FeNO(CN)5]3 andcis-[Co(NH3)(en)2(H2O)][Co(CN)6] have been synthesized and by anation in the solid state the corresponding new dinuclear complexes with a cyano bridgecis- ortrans-[(NH3)(en)2Co-NC-M(CN)3]2 [M(CN)4] (M = Ni, Pd or Pt);cis-, trans-[(NH3)(en)2Co-NC-FeNO(CN)4]2[FeNO(CN)5] andcis-[(NH3)(en)2Co-NC-Co(CN)5 have been prepared. The complexes have been characterized by chemical analysis, t.g. measurements, and by i.r. and electronic spectroscopy. With [Ni(CN)4][2− and [Co(CN)in]6 3− only thecis-isomer is produced; with [Pd(CN)4]2−, [Pt(CN)4]2− and [FeNO(CN)5]2− thetrans- isomer is the dominant species. The dinuclear complex derived from [Pt(CN)4]2− shows strong Pt-Pt interactions both in the solid state and in solution.
- University of Barcelona Spain
selected citations These citations are derived from selected sources.This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).6 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Average influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Average impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Average
Citations provided by BIP!Popularity provided by BIP!