Comments on ?parabolic oxidation of metals to metal deficit oxides?

descriptionPublicationkeyboard_double_arrow_right Article 01 Jun 1972 English Publisher:Springer Science and Business Media LLCJournal:Oxidation of Metals, volume 4, pages 85-89 (issn: 0030-770X, eissn: 1573-4889,

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Authors: P. Sarrazin; J. Besson;

doi: 10.1007/bf00612165

Comments on ?parabolic oxidation of metals to metal deficit oxides?

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Abstract

Two fundamental errors are pointed out in a recent paper by Bridges and Fassell Jr1. Both concern the application of the law of mass action to a heterogeneous equilibrium, the first in the case of the sorption equilibrium, the second for the external interfacial reaction. These errors lead to an incorrect derivation of the pressure law for the oxidation of nickel and cobalt.

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École Normale Supérieure
France

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