Oximes and nitriles of cardenolides

descriptionPublicationkeyboard_double_arrow_right Article 01 Sep 1983 English Publisher:Springer Science and Business Media LLCJournal:Chemistry of Natural Compounds, volume 19, pages 572-576 (issn: 0009-3130, eissn: 1573-8388,

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Authors: I. F. Makarevich; M. V. Mokrouz; L. Ya. Topchii; I. P. Kovalev; V. E. Sokolova; Yu. I. Gubin; N. P. Bublik; +1 Authors

doi: 10.1007/bf00576086

Oximes and nitriles of cardenolides

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Abstract

The influence of the oximation of cardenolides and the production of 10-cyanocardenolides on their biological activity has been studied. The prefered conformation of strophanthidin 19-aldoxime has been established; it has chelate fragment as the result of the orientation in the same direction of the nitrogen atom of the oxime group and the hydroxy groups at C-3 and C-5.

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