Synthesis of pregnane derivatives

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1984 English Publisher:Springer Science and Business Media LLCJournal:Chemistry of Natural Compounds, volume 20, pages 302-304 (issn: 0009-3130, eissn: 1573-8388,

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Authors: E. V. Popova; V. A. Andryushina; G. S. Grinenko;

doi: 10.1007/bf00575752

Synthesis of pregnane derivatives

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Abstract

Pregnane derivatives have been obtained from the cyanohydrins of androst-4-en-3, 17-dione and of 3β-acetoxyandrost-5-en-17-one. It has been shown that when both a nitrile group and an ethylenedioxy group are present in an androstane derivative a Grignard reaction in anisole takes place simultaneously at the two groups.

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