Furocoumarins ofCnidium dubium

descriptionPublicationkeyboard_double_arrow_right Article 01 Nov 1966 English Publisher:Springer Science and Business Media LLCJournal:Chemistry of Natural Compounds, volume 2, pages 307-310 (issn: 0009-3130, eissn: 1573-8388,

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Authors: N. F. Komissarenko; V. T. Chernobai;

doi: 10.1007/bf00564211

Furocoumarins ofCnidium dubium

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Abstract

1. Paper chromatography has shown that the fruit ofC. dubium contains not less than eight substances of coumarinic nature; six of these (A, B, C, D, E, and H) have been isolated in the crystalline state. 2. Substances B, D, and E are identical with isoimperatorin, imperatorin, and oxypeucedanin, respectively. Some properties of substance H have been determined. Prangenin [F] has been detected in the fruit ofC. dubium by paper chromatography. 3. The structure of two new compounds has been established: substance A (cnidicin) (I) is 5, 8-di-(γ, γ-dimethylallyloxy) psoralen, and substance C (cnidilin) (II) is 5-(γ, γ-dimethylallyloxy)-8-methoxypsoralen.

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