Magnetooptic activity and symmetry of petroleum vanadyl porphyrins

descriptionPublicationkeyboard_double_arrow_right Article 01 Nov 1992 English Publisher:Springer Science and Business Media LLCJournal:Russian Physics Journal, volume 35, pages 1,004-1,008 (issn: 1064-8887, eissn: 1573-9228,

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Authors: A. A. Latyshev; V. N. Medvedev; V. O. Nekuchaev;

doi: 10.1007/bf00559093

Magnetooptic activity and symmetry of petroleum vanadyl porphyrins

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Abstract

We report magnetooptic rotation and magnetic circular dichroism spectra in the vicinity of the absorption bands at 17410 cm−1 and 16760 cm−1 in chloroform solutions of petroleum vanadyl porphyrin. Using the moment method, we estimate the original splitting and the z-component of the magnetic moment of the 11E1u level for both synthetic and petroleum vanadyl porphyrins. We conclude that petroleum vanadyl porphyrins exhibit D2h symmetry.

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