Synthesis of cis-1-methyl-2-aryl-3-aroylaziridines

descriptionPublicationkeyboard_double_arrow_right Article 01 Oct 1980 English Publisher:Springer Science and Business Media LLCJournal:Chemistry of Heterocyclic Compounds, volume 16, pages 1,025-1,027 (issn: 0009-3122, eissn: 1573-8353,

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Authors: I. G. Tishchenko; O. N. Bubel'; V. A. Konovalov;

doi: 10.1007/bf00496602

Synthesis of cis-1-methyl-2-aryl-3-aroylaziridines

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Abstract

trans-1-Methyl-2-aryl-3-aroylaziridines readily undergo epimerization to give the corresponding cis isomers in high yields in the presence of catalytic amounts of quaternary ammonium bases (trimethylbenzylammonium or triethylmethylammonium hydroxide). The structures of the compounds obtained were established on the basis of the IR and PMR spectra and the results of elementary analysis.

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