Nitration of 1-methyl-2-pyridone

descriptionPublicationkeyboard_double_arrow_right Article 01 Dec 1973 English Publisher:Springer Science and Business Media LLCJournal:Chemistry of Heterocyclic Compounds, volume 9, pages 1,512-1,514 (issn: 0009-3122, eissn: 1573-8353,

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Authors: N. P. Shusherina; T. I. Likhomanova;

doi: 10.1007/bf00477568

Nitration of 1-methyl-2-pyridone

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Abstract

Nitration of 1-methyl-2-pyridone with 70% nitric acid or fuming nitric acid at 0–20°C proceeds in the 3 and 5 positions to give a mixture of mononitro isomers, the structures of which were proved by PMR spectroscopy. Mainly 3,5-dinitro-1-methyl-2-pyridone is formed by the action of fuming nitric acid or a nitrating mixture at 90°.

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Lomonosov Moscow State University
Russian Federation

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