Ionic hydrogenation of benzofurans

descriptionPublicationkeyboard_double_arrow_right Article 01 Nov 1975 English Publisher:Springer Science and Business Media LLCJournal:Chemistry of Heterocyclic Compounds, volume 11, pages 1,261-1,263 (issn: 0009-3122, eissn: 1573-8353,

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Authors: �. A. Karakhanov; E. A. Dem'yanova; E. G. Shkarin; E. A. Viktorova;

doi: 10.1007/bf00474449

Ionic hydrogenation of benzofurans

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Abstract

Benzofurans are arranged in the order 2-methylbenzofuran > 3-methylbenzofuran > benzofuran with respect to the case with which they undergo ionic hydrogenation. Benzofuran and 2-methylbenzofuran are protonated in the 3 position of the heterocyclic ring, whereas 3-methylbenzofuran is protonated in the 2 position. Individual monodeuterated 2,3-dihydrobenzofurans can be obtained in high yields by ionic hydrogenation.

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Lomonosov Moscow State University
Russian Federation

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