Properties of furoxans monosubstituted with adamantanes

descriptionPublicationkeyboard_double_arrow_right Article 01 Feb 1988 English Publisher:Springer Science and Business Media LLCJournal:Chemistry of Heterocyclic Compounds, volume 24, pages 217-220 (issn: 0009-3122, eissn: 1573-8353,

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Authors: M. I. Kalinina; I. K. Moiseev;

doi: 10.1007/bf00473336

Properties of furoxans monosubstituted with adamantanes

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Abstract

Furoxans monosubstituted with a series of adamantanes have been obtained by oxidation of anti-[1-(3-R-adamantyl)]-amphi-glyoximes. Depending on the conditions 4-(1-adamantyl)furoxan is partially isomerized to 3-(1-adamantyl)furoxan or by increasing the time of boiling and concentration of furoxan in p-xylene is isomerized to the thermodynamically stable 3-(1-adamantyl)-1,2,4-oxadiazol-5-one.

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Samara State Technical University
Russian Federation

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