Anion-radical complexes with perimidine redox ligands

descriptionPublicationkeyboard_double_arrow_right Article 01 Dec 1987 English Publisher:Springer Science and Business Media LLCJournal:Chemistry of Heterocyclic Compounds, volume 23, pages 1,369-1,369 (issn: 0009-3122, eissn: 1573-8353,

Copyright policy )

Authors: E. S. Klimov; I. V. Karsanov; A. V. Shpakov; V. Kh. Sabanov; O. Yu. Okhlobystin;

doi: 10.1007/bf00472271

Anion-radical complexes with perimidine redox ligands

- Summary
- Metrics

Abstract

Bis(9~oxo-2-perimidyl) (I) is easily reduced by alkali metals and thallium in THF to generate the corresponding anion radicals and dianions. The anion radical with a potassium r was characterized by its EPR spectrum, which was indicative of delocalization of the unpaired electron density across the perimidine fragment, based on the following hyperfine splitting constants: aN, = 0.36; aN 3 = 0.30; aH 4,~,7 = 0.24; aHS, s = 0~ mT; g factor 2~176

Related Organizations

North Ossetian State University
Russian Federation

Impact byBIP!

	selected citations These citations are derived from selected sources. This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	1
	popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.	Average
	influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	Average
	impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.	Average