Clinoenstatite lamellae are found to be distributed in three distinct patterns that define three microstructural types. There are regions of the crystal devoid of lamellae and these correspond to ordered or O-orthopyroxene. When the lamellae are present but not in any periodic arrangement, disordered or D-orthopyroxene is identified. In some areas, the lamellae are spaced periodically and these are regions of “superlattice” orthopyroxene. These microstructural types explain all previous X-ray results on orthopyroxenes. Microstructural differences between low and high calcium orthopyroxenes are discussed.