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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Polymer Bulletin
Article . 1981 . Peer-reviewed
License: Springer TDM
Data sources: Crossref
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Sol fraction and swelling analysis of cis-1,4-polybutadiene networks produced by high-energy irradiation

Authors: G.A. Alvarez; H.-J. Cantow; A. Hasenhindl;

Sol fraction and swelling analysis of cis-1,4-polybutadiene networks produced by high-energy irradiation

Abstract

Soluble fraction and equilibrium swelling in toluene were investigated on cis-1,4-polybutadiene networks being crosslinked in vacuo by 60Co-irradiation. Analysis of the sol fraction data by means of INOKUTI's equation reveals a drastic increase of the degradation-crosslink ratio for samples unpurified prior to crosslinking. Furthermore, the network crosslinking susceptibility depends on purification, although it is rather temperature insensitive for irradiation above the glass transition temperature of the rubber. The statistics of creation of crosslinks can be examined by suitable modification of INOKUTI's theory. From the present data it may be concluded that chain reaction crosslinking is negligible. The FLORY-REHNER formula for swelling equilibrium fails to reproduce the data at the cross link densities studied, but introducing a free end correction, the formula becomes applicable, with some over-correction. Hence the crosslink susceptibility could be obtained independently if the polymer-solvent heat interaction parameter were known. Additionally, the assumption about the proportionality of the crosslink density with radiation dose has been successfully tested by the swelling experiments.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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