Bent-over buoyant jets distorted by a crosscurrent develop a vortex pair structure and can bifurcate to produce two distinct lobes which diverge from one another downwind. The region downwind of the source between the lobes has relatively low proportions of discharged fluid. Factors invoked by previous workers to cause or enhance bifurcation include buoyancy, release of latent heat at the plume edge by evaporating water droplets, geometry and orientation of the source, and the encounter with a density interface on the rising path of the plume. We suggest that the pressure distribution around the vortex pair of a rising plume may initially trigger bifurcation. We also report new experimental observations confirming that bifurcation becomes stronger for stronger bent-over plumes, identifying that bifurcation can also occur for straight-edged plumes but gradually disappears for stronger plumes which form a gravity current at their final level and spread for a significant distance against the current. Observations from satellites and the ground are reviewed and confirm that volcanic plumes can show bifurcation and a large range of bifurcation angles. Many of the bifurcating plumes spread out at the tropopause level and suggest the tropopause may act on the plumes as a density interface enhancing bifurcation. Even for quite moderate bifurcation angles, the two plume lobes become rapidly separated downwind by distances of tens of kilometers. Such bifurcating plumes drifting apart can only result in bilobate tephra fall deposits. The tephra fall deposit from the 16 km elevation, SE spreading, bifurcating volcanic plume erupted on 15 May 1981 from Mt Pagan was sampled by previous workers and clearly displayed bilobate characteristics. Examples of bilobate tephra fall deposits are reviewed and their origin briefly discussed. Bilobate deposits are common and may result from many causes. Plume bifurcation should be considered one of the possible mechanisms which can account for come examples of bilobate tephra fall deposits.