Polymeric schiff's base chelates and their precursors 8a), some cobalt chelates as catalysts for the isomerization of quadrycyclane to norbornadiene

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1985 English Publisher:Springer Science and Business Media LLCJournal:Polymer Bulletin, volume 13 (issn: 0170-0839, eissn: 1436-2449,

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Authors: D. W�hrie; P. Buttner;

doi: 10.1007/bf00264241

Polymeric schiff's base chelates and their precursors 8a), some cobalt chelates as catalysts for the isomerization of quadrycyclane to norbornadiene

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Abstract

Starting with Z-2, 3-diamino-2-butenedinitrile as diamine component the synthesis of the low molecular N,N,O,O-chelate 3.Co and its ligand 3 is optimized. An easy synthesis of the chelate 8.Co covalently bound on macroreticular resins is presented. The chelates 8.Co are the most active heterogenous catalysts for the valence isomerization of quadricyclane to norbornadiene today.

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University of Bremen
Germany

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