Optically active alternating copolymer and Diels-Alder adduct

descriptionPublicationkeyboard_double_arrow_right Article 01 Oct 1980 English Publisher:Springer Science and Business Media LLCJournal:Polymer Bulletin, volume 3, pages 285-290 (issn: 0170-0839, eissn: 1436-2449,

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Authors: Eiichi Kobayashi; Shunichi Matsumura; Junji Furukawa;

doi: 10.1007/bf00254875

Optically active alternating copolymer and Diels-Alder adduct

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Abstract

Asymmetric induction copolymerization and Diels-Alder reaction were investigated between acrylic monomer and olefin or diolefin with use of an optically active aluminum compound as the complexing agent. In the copolymerization, only benzofuran gave an optically active alternating copolymer, while butadiene and indene gave alternating copolymers but with no optical activity. EtAlCl2-l-menthol was the most effective complexing agent. However, EtAlCl2-d-neomenthol was ineffective.

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