
doi: 10.1007/bf00208867
The same physical phenomenon that gives rise to the increase in the electrostatic self-energy of an ion within a narrow water-filled pore is shown to result in interionic electrical interactions within the pore that are much stronger and of longer range than those between the same ions in the same solution in bulk. Because of the much enhanced attraction between ions of opposite charge within the pore the formation of ion pairs becomes likely, even for strong electrolytes that are fully dissociated in the same solution when not spatially confined. Some predicted consequences of ion pair formation in narrow pores that may be experimentally detected are discussed. It is shown that, in a simple passive pore, due to ion pair formation, an Ussing unidirectional flux ratio exponent of less than 1 is predicted. This is usually thought to characterize a carrier rather than a pore.
| selected citations These citations are derived from selected sources. This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | 1 | |
| popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network. | Average | |
| influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | Average | |
| impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network. | Average |
