Pyrometasomatic lead-zinc ore deposits of the Kamioka mine occur in the Hida metamorphic complex of central Japan. The pyrometasomatic ore deposition was followed by small scale hydrothermal ore deposition. Flaky graphite characteristically occurs in skarn, ores and in the surrounding crystalline limestone. δ13C values of graphite in the skarn and the ores are close to those of graphites in the crystalline limestone. Graphite in the skarn and ores is considered to be remains of graphite in the crystalline limestone which was replaced by the skarn and the ores. At the pyrometasomatic stage, the oxygen fugacity of fluid would control the carbon isotopic composition of calcite precipitated. On the assumption that graphite played a role of oxygen buffer, the oxygen fugacity of the fluid was estimated to be from 10−31,4 to 10−301 bars at 350 °C and total pressure of 1,000 bars. The predominant carbon species in the fluid would be carbon dioxide. The δ13C value of total carbon in fluid was estimated to be −3.6±1.7‰ (PDB) for the Tochibora and Maruyama deposits of the Kamioka mine, and the oxygen fugacity in the fluid was probably constant during the pyrometasomatic stage. It is likely that an important source of carbon was the carbon remained after the decarbonation of crystalline limestone. Oxygen isotopic studies on calcite of pyrometasomatic and hydrothermal stages revealed that meteoric water was an important source for most of the oxygen in fluid of both stages.