Iron(III) Spin Crossover Compounds
Iron(III) Spin Crossover Compounds
In this chapter, selected results obtained so far on Fe(III) spin crossover compounds are summarized and discussed. Fe(III) spin transition materials of ligands containing chalcogen donor atoms are considered with emphasis on those of N,N-disubstituted-dithiocarbamates, N,N-disubstituted-XY-carbamates (XY=SO, SSe, SeSe), X-xanthates (X=O, S), monothio-beta-diketonates and X-semicarbazones (X=S, Se). In addition, attention is directed to Fe(III) spin crossover systems of multidentate Schiff base-type ligands. Examples of spin inter-conversion in Fe(III) compounds induced by light irradiation are given.
- University of Tsukuba Japan
- University of Groningen Netherlands
- Kyushu University Japan
SOLVATE SERIES <FE(3-OET-SALAPA)2>(CLO4).S, LARGE THERMAL HYSTERESIS, ASYMMETRIC LIGAND FIELDS, QUADRIDENTATE SCHIFF-BASES, dithiocarbamate, thiosemicarbazone, Schiff base, spin crossover, RAY CRYSTAL-STRUCTURE, DEPENDENT MAGNETIC-BEHAVIOR, Fe(III), ELECTRON-PARAMAGNETIC-RES, TRANSITION-METAL COMPLEXES, STATE RELAXATION DYNAMICS, MONOTHIO-BETA-DIKETONES
SOLVATE SERIES <FE(3-OET-SALAPA)2>(CLO4).S, LARGE THERMAL HYSTERESIS, ASYMMETRIC LIGAND FIELDS, QUADRIDENTATE SCHIFF-BASES, dithiocarbamate, thiosemicarbazone, Schiff base, spin crossover, RAY CRYSTAL-STRUCTURE, DEPENDENT MAGNETIC-BEHAVIOR, Fe(III), ELECTRON-PARAMAGNETIC-RES, TRANSITION-METAL COMPLEXES, STATE RELAXATION DYNAMICS, MONOTHIO-BETA-DIKETONES
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