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Structures of Ice and Water as Investigated by Infrared Spectroscopy

Authors: E. Whalley;

Structures of Ice and Water as Investigated by Infrared Spectroscopy

Abstract

The infrared spectra of ice and liquid water and the interpretation of them is reviewed. The best understood band is the translational lattice band in ice below 350 cm-1, largely because the translational lattice vibrations can be taken to be mechanically regular in a first approximation, but electrically irregular owing to the orientational disorder. This allows a relatively simple dynamical and electrical theory to be worked out that is necessary for the interpretation. The rotational vibrational and the O—H stretching bands are less well understood, and there is essentially no detailed interpretation that can be reasonably maintained. The spectrum of the liquid is even less well understood, except in the most general terms, and, contrary to the conclusions of a number of papers, there is little reasonably well based structural information to be obtained at present.

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    citations
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    17
    popularity
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    Average
    influence
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    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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Found an issue? Give us feedback
citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
17
Average
Top 10%
Average
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