Abstract In describing the phonotactics (patterning of phonemes) of English syllables, linguists have focused on absolute restrictions concerning which phonemes may occupy which slots of the syllable. To determine whether probabilistic patterns also exist, we analyzed the distributions of phonemes in a reasonably comprehensive list of uninflected English CVC (consonant–vowel–consonant) words, some 2001 words in all. The results showed that there is a significant connection between the vowel and the following consonant (coda), with certain vowel–coda combinations being more frequent than expected by chance. In contrast, we did not find significant associations between the initial consonant (onset) and the vowel. These findings support the idea that English CVC syllables are composed of an onset and a vowel–coda rime. Implications for lexical processing are discussed.