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Journal of Colloid and Interface Science
Article
License: CC BY NC
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Journal of Colloid and Interface Science
Article . 2002 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Frequency-Dependent Electroosmosis

Authors: Philip M, Reppert; Frank Dale, Morgan;

Frequency-Dependent Electroosmosis

Abstract

This paper presents a theory for frequency-dependent electroosmosis. It is shown that for a closed capillary the electroosmosis frequency-dependent ratio of DeltaV/DeltaP is constant with increasing frequency until inertial effects become prevalent, at which time DeltaV/DeltaP starts to decrease with increasing frequency. The frequency response of the electroosmosis coupling coefficient is shown to be dependent on the capillary radius. As the capillary radius is made smaller, inertial effects start to occur at higher frequencies. As part of this paper, frequency-dependent electroosmosis is compared to frequency-dependent streaming potentials. In this comparison it is shown that inertial effects start to become more prevalent at higher frequencies for the closed capillary frequency-dependent electroosmosis case than for the frequency-dependent streaming potential case in the same capillary. It is also shown that this difference is due to a second viscosity (transverse) wave that emanates from the velocity zero within the capillary for the electroosmosis case. The second viscosity wave superposes with the viscosity wave that emanates from wall of the capillary to effectively reduce the hydraulic radius of the capillary. Data are presented for a 0.127-mm capillary to support the findings in this paper.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
42
Top 10%
Top 10%
Top 10%
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