
AbstractSolid perrhenic acid monohydrate has been characterized by X‐ray single crystal structure analysis (300 K). HReO4 · H2O, Mr = 269.23, tetragonal, I41/a, Scheelite‐type (CaWO4), a = 5.8320(2) Å, c = 12.9384(6) Å, V = 440.06(5) Å3, Z = 4, Dx = 4.063 g cm−3, X‐ray wavelength λ (MoKα) = 0.71069 Å The structure consists of [ReO4]−‐tetrahedra and oxonium ions linked by hydrogen bridges to form a three‐dimensional network.
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