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Small Structures
Article . 2023 . Peer-reviewed
License: CC BY
Data sources: Crossref
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Small Structures
Article . 2023
Data sources: DOAJ
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Research Collection
Article . 2023
License: CC BY
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Anisotropic, Strong, and Thermally Insulating 3D‐Printed Nanocellulose–PNIPAAM Aerogels

Authors: Yannick Nagel; Deeptanshu Sivaraman; Antonia Neels; Tanja Zimmermann; Shanyu Zhao; Gilberto Siqueira; Gustav Nyström;
APC: 2,377 EUR

Anisotropic, Strong, and Thermally Insulating 3D‐Printed Nanocellulose–PNIPAAM Aerogels

Abstract

Cellulose is a promising candidate for the fabrication of superinsulating materials, which would be of great interest for thermal management applications as well as for the scientific community. Until now, the production of strong cellulose‐based aerogels has been dominated by traditional manufacturing processes, which have limited the possibilities to achieve the structural control and mechanical properties seen in natural materials such as wood. In this work, we show a simple but versatile method to fabricate cellulose aerogels in intricate geometries. We take advantage of the 3D printing technique direct ink writing to control both the shape and the thermal‐mechanical properties of the printed cellulose‐based hydrogel inks. Moreover, the shear forces involved in the extrusion process allow us to impart an anisotropic nanostructure to the printed samples. By solvent exchange and supercritical drying, the hydrogel parts are then transformed into stable aerogels. Using X‐ray diffraction analysis, mechanical tests and thermal conductivity tests, our 3D printed aerogels are shown to exhibit directionally dependent thermal‐mechanical properties higher than those reported for earlier cellulose‐based aerogels. These characteristics enable us to fabricate customized structures that can be precisely tailored for their application as load‐bearing insulating materials for thermal management.

Country
Switzerland
Keywords

Chemistry, aerogels, Physics, QC1-999, 3D printing; aerogels; cellulose nanocrystals; hydrogels, 3D printing, QD1-999, cellulose nanocrystals, hydrogels

  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    15
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Average
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
15
Top 10%
Average
Top 10%
Green
gold