
AbstractCarbon expanded austenite synthesized through carburizing of austenitic stainless steel powder at 380°C was annealed at 470°C and investigated with extended X‐ray absorption fine structure (EXAFS) and synchrotron powder diffraction (SPD). SPD showed that the samples consisted of carbon expanded austenite and Hägg carbide, χ‐M5C2. EXAFS showed that the Cr atoms were mainly present in environments similar to the carbides Hägg χ‐M5C2 and M23C6. The environments of the Fe and Ni atoms were concluded to be largely metallic austenite.
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