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On the luminescence of lanthanide decatungstates. III. Tetrabutylammonium and brucinium salts

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 01 Jan 1982 English Publisher:WileyJournal:Recueil des Travaux Chimiques des Pays-Bas, volume 101, pages 434-437 (issn: 0165-0513, eissn: 0165-0513,

Authors: G. Blasse; F. Zonnevijlle;

doi: 10.1002/recl.19821011202 , 10.1002/chin.198310303

On the luminescence of lanthanide decatungstates. III. Tetrabutylammonium and brucinium salts

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Abstract

AbstractThe luminescence properties of the following decatungstates have been investigated: X9LnW10O36 (X = tetra‐n‐butylammonium or brucinium; Ln = Sm, Eu, Dy). Due to the large X ions, the separation between the lanthanide ions is very large. Consequently no interaction between these ions occurs, not even in the case of Sm and Dy. The tetra‐n‐butylammonium salts contain a small number of alkali metal ions. The emission of Eu3+ has been used to analyse the composition in more detail. The brucinium salts do not luminesce efficiently upon tungstate excitation, since the excitation energy is lost, for the greater part, in the brucinium ions.

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