Powered by OpenAIRE graph
Found an issue? Give us feedback
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Rapid Communications...arrow_drop_down
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Rapid Communications in Mass Spectrometry
Article . 2020 . Peer-reviewed
License: Wiley Online Library User Agreement
Data sources: Crossref
versions View all 2 versions
addClaim

Absolute isotope ratios defining isotope scales used in isotope ratio mass spectrometers and optical isotope instruments

Authors: Grzegorz Skrzypek; Philip J. H. Dunn;

Absolute isotope ratios defining isotope scales used in isotope ratio mass spectrometers and optical isotope instruments

Abstract

Rationale The isotope delta is calculated from the isotope ratio of a sample and the absolute isotope ratio of the zero reference point defining each stable isotope international scale ( R std ). Therefore, R std requires accurate determination. However, the literature contains a large number of R std values, and selection of different R std may lead to inconsistency in reporting and recalculating stable isotope results. Methods We reviewed R std used in the proprietary software provided by the manufacturers of stable isotope instruments commonly employed for analyses of stable HCNOS compositions. We compared the R std values and assessed the potential implications of using different R std and the normalization versus tank working gas standard for consistency in reporting stable isotope results. Results Different R std values are used by different manufacturers of stable isotope analytical instruments. For R ( 2 H/ 1 H) VSMOW two different but very similar values are used, 0.00015575 and 0.00015576; for R ( 13 C/ 12 C) VPDB three different values are used, 0.0111802, 0.0112372 and 0.01118028; and for R ( 15 N/ 14 N) Air‐N2 two values, 0.0036782 and 0.0036765, are used. All manufacturers are using the same value for R ( 18 O/ 16 O) VSMOW , 0.00200520, but three different values for R ( 18 O/ 16 O) VPDB , 0.002067200, 0.00208835 and 0.002088349. For R ( 34 S/ 32 S) VCDT four different R std are used, 0.0441509, 0.0441626, 0.044162589 and 0.0441520597. Conclusions The use of different R std values may lead to differences in the isotope delta values obtained if the normalization versus working standard gas is applied. For the range of R std used in proprietary software, the potential differences are lowest for oxygen (< 0.002 ‰) and nitrogen (< 0.001 ‰), and highest for carbon (0.107 to 0.112 ‰) and sulfur (0.023 ‰). Evaluation of the existing R std values and recommendations for the best estimates are highly desirable to ensure worldwide consistency in stable isotope data reporting.

Related Organizations
  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    11
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Average
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
11
Top 10%
Average
Top 10%
bronze