Photolysis of acifluorfen in aqueous solution

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1991 Italy English Publisher:WileyJournal:Pesticide Science, volume 32, pages 1-5 (issn: 0031-613X, eissn: 1096-9063,

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Authors: PUSINO, Alba; GESSA C.;

doi: 10.1002/ps.2780320102

handle: 11388/49135

Photolysis of acifluorfen in aqueous solution

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Abstract

AbstractThe photolysis of acifluorfen, sodium 5‐[2‐chloro‐4‐(trifluoromethyl)‐phenoxy]‐2‐nitrobenzoate (I) in aqueous solution afforded only 2‐chloro‐1‐(4‐nitrophenoxy)‐4‐trifluoromethylbenzene (II) arising from photodecarboxylation. The reaction followed first‐order kinetics, though the photo‐reaction rate was solvent‐dependent. A mechanism that accounts for the formation of the product is proposed.

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Italy

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University of Sassari
Italy

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