
AbstractThe synthesis and properties of various 1,2,4,5‐tetrazine explosives and energetic materials are described. These are the nitrate and perchlorate salts of 3,6‐diguanidino‐1,2,4,5‐tetrazine, the nitrate and perchlorate salts of 3,6‐diguanidino‐1,2,4,5‐tetrazine‐1,4‐di‐N‐oxide, 3,6‐bis(1H‐1,2,3,4‐tetrazol‐5‐ylamino)‐1,2,4,5‐tetrazine and its 1,4‐di‐N‐oxide derivative, 3,3′‐azobis(6‐amino‐1,2,4,5‐tetrazine) and its oxidation products.
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