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Thermal decomposition products of polymethylene

Name: Thermal decomposition products of polymethylene
Keywords: pyrolyse, chromatographie, polimethylpentene, polyéthylène haute densité, Combustion, chromatography, free radicals, high density polyethylene, pyrolysis, polyméthylpentene

descriptionPublicationkeyboard_double_arrow_right Article 01 Feb 1968 Canada English Publisher:WileyJournal:Journal of Polymer Science Part B: Polymer Letters, volume 6, pages 357-361 (issn: 0449-2986, eissn: 1542-6254,

Authors: Tsuchiya, Y.; Sumi, K.;

doi: 10.1002/pol.1968.110060508 , 10.1002/pol.1968.150060211

Thermal decomposition products of polymethylene

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Abstract

AbstractDecomposition products of polymers have been determined by many investigators, but the results are often conflicting because of difficulties in analyzing a large number of products. A comprehensive analysis of the volatile thermal decomposition products of high‐density polyethylene has been made with the latest techniques in gas chromatography. The formation of products is explained on the basis of free‐radical mechanism. The predominant process in the formation of volatiles appears to be intramolecular transfer of radicals, in which isomerization by a coiling mechanism plays an important role in determining the relative quantities of each product.

Country

Canada

Related Organizations

National Academies of Sciences, Engineering, and Medicine
United States
National Research Council Canada
Canada

Keywords

pyrolyse, chromatographie, polimethylpentene, polyéthylène haute densité, Combustion, chromatography, free radicals, high density polyethylene, pyrolysis, polyméthylpentene, radical libre

Impact byBIP!

	citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	98
	popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.	Top 10%
	influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	Top 1%
	impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.	Average

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Top 10%

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