Evaluation of molecular weight averages resulting from random crosslinking and chain scission processes for wide schulz‐zimm distributions

descriptionPublicationkeyboard_double_arrow_right Article 01 Oct 1963 English Publisher:WileyJournal:Journal of Polymer Science Part A: General Papers, volume 1, pages 3,175-3,182 (issn: 0449-2951, eissn: 1542-6246,

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Authors: A. M. Kotliar;

doi: 10.1002/pol.1963.100011012

Evaluation of molecular weight averages resulting from random crosslinking and chain scission processes for wide schulz‐zimm distributions

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Abstract

AbstractThe Monte Carlo sampling technique was used to evaluate the resulting molecular weight averages and the intrinsic viscosity for wide Schulz‐Zimm distribution polymers, in the range P̄w/P̄n ≦ 11, undergoing random chain scission and crosslinking processes. The results may also be used to evaluate the initial distribution and are generally more reliable than the use of fractionation data.

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