AbstractPolymers under discussion can be represented by [CH2)nR]p where R is CH2, CF2, O, S or CH = CH; and where n can vary from 0 to ∞. The copolymer, P(ethylene‐alt‐TFE) is also included. These polymers tend to be highly crystalline with resultant confusion about their Tg and hence their Tg/Tm values and a clarification scheme is proposed in which it is considered that each such polymer has a double glass transition, Tg(L)/f(χc), Tg(U) = F(χc); and a sub‐glass T<Tg(L) at 0.75 Tg(L), where F(χc) signifies a function of fractional crystallinity, χc. T<Tg(L) and Tg(L) increase linearly with Tm. The ratio, Tg(L)/Tm, is therefore, not a constant but is close to 0.5. T<Tg(L)/Tg(L) is also not a constant but is close to 0.75. Tg(U) lies within a wedge whose top and bottom sides increase with Tm. The premelting, intracrystalline transition temperature, Tαc, is also a linear function of Tm. It is suggested that the scheme outlined above should help to resolve uncertainties in assigning transition temperatures for unsubstituted polymers. The low Tg/Tm values for these polymers is discussed in terms of their small da/dc ratios and small crosssectional areas per chain.