Abstract Blends composed of poly(ethylene terephthalate) (PET) and poly(butylene terephthalate) (PBT) were melt‐mixed in a Brabender cam mixer at different mixing speeds. The glass transition ( T g ) and the crystallization behavior of the blends from glassy state were studied using DSC. It was found that although the blends had the same composition and exhibited the similar T g , their properties of crystallization could be different; some exhibited a single crystallization peak and some exhibited multiple crystallization peaks depending upon experimental conditions. Results indicated that the behavior of crystallization from glassy state were influenced by entanglement and transesterification of chains. The crystallization time values were obtained over a wide range of crystallization temperature. From curve fitting, the crystallization time values and the temperature, at which the crystallization rate reaches the maximum, were found.