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Selective O‐Acylation of Enol Silyl Ethers with Acyl Fluorides Catalyzed by Fluoride Ions Derived from Potassium Fluoride and 18‐Crown‐6

descriptionPublicationkeyboard_double_arrow_right Article 29 Jan 2024 English Publisher:WileyJournal:ChemistryOpen, volume 13 (issn: 2191-1363, eissn: 2191-1363, Copyright policy )
Authors: Norio Sakai; Kota Watanabe; Haruka Mori; Yuki Maegawa; Ryuki Takeuchi; Yohei Ogiwara; Kento Ishida;

doi: 10.1002/open.202300300

pmid: 38286634

pmc: PMC11230931

Selective O‐Acylation of Enol Silyl Ethers with Acyl Fluorides Catalyzed by Fluoride Ions Derived from Potassium Fluoride and 18‐Crown‐6

Abstract

AbstractThe fluoride ion‐catalyzed selective O‐acylation of enol silyl ethers with acyl fluorides using KF and 18‐Crown‐6 is described herein. This catalytic system facilitated the practical and facile reaction of a variety of enol silyl ethers derived from aromatic/aliphatic ketones and aldehydes with acyl fluorides to afford useful and valuable enol esters.

Related Organizations
Keywords

Enol silyl ether, Chemistry, Acyl fluoride, O-Acylation, Vinyl ester, QD1-999, Fluoride ion, Research Article

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    popularity
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    influence
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
1
Average
Average
Average
Green
gold