Advantages of Surface‐Initiated ATRP (SI‐ATRP) for the Functionalization of Electrospun Materials
Copyright policy )Advantages of Surface‐Initiated ATRP (SI‐ATRP) for the Functionalization of Electrospun Materials
AbstractSurface‐initiated atom transfer radical polymerization (SI‐ATRP) is successfully applied to electrospun constructs of poly(L‐lactide). ATRP macroinitiators are adsorbed through polyelectrolyte complexation following the introduction of negative charges on the polyester surface through its blending with a six‐armed carboxy‐terminated oligolactide. SI‐ATRP of glycerol monomethacrylate (GMMA) or 2‐(N,N‐diethylamino)ethyl methacrylate (DEAEMA) allows then to grow surface films with controllable thickness, and in this way also to control the wetting and interactions of the construct.
- University of Milan Italy
- University of Catania Italy
- Alma Mater Studiorum University of Bologna Italy
- University of Salford United Kingdom
wetting, Free Radicals, Surface Properties, Polyesters, Nanofibers, ATRP, surface-initiated polymerization, contact angle; electrospinning; surface initiated polymerization; wetting, ATRP,; CONTACT ANGLE; ELECTROSPINNING; SURFACE-INITIATED POLYMERIZATION; WETTING, ATRP; contact angle; electrospinning; surface-initiated polymerization; wetting, Methacrylates, Adsorption, contact angle, electrospinning
wetting, Free Radicals, Surface Properties, Polyesters, Nanofibers, ATRP, surface-initiated polymerization, contact angle; electrospinning; surface initiated polymerization; wetting, ATRP,; CONTACT ANGLE; ELECTROSPINNING; SURFACE-INITIATED POLYMERIZATION; WETTING, ATRP; contact angle; electrospinning; surface-initiated polymerization; wetting, Methacrylates, Adsorption, contact angle, electrospinning
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