AbstractAnodic coupling of the dihydrobenzodipyrrole isomers 1H,8H‐pyrrolo[3,2‐g]indole (1), 1H,7H‐pyrrolo[3,2‐f]indole (2), and 1H,5H‐pyrrolo[2,3‐f]indole (3) in 0,1 M tetraethylammonium perchlorate in acetonitrile produces polymeric films which are reversibly oxidized around 0,3 V vs. Ag/Ag+ with 0,5 electrons per monomeric unit. IR reflectance, UV‐vis and cyclic voltammetry show that the oxidized polymers undergo easy overoxidation at the benzene ring without affecting the charge storage ability. Conductivities (0,2–5 Ω−1 · cm−1) are higher than those presented by chemically prepared samples (10−4 – 10−1 Ω−1 · cm−1) and are attributed to more ordered structures of the polymers.