
pmid: 1152469
AbstractFluorescent polymers were obtained by oxidizing partly emulsified linolenic acid with different oxidants. The speed of formation of polymers differed for the various oxidants, and the difference was not a simple function of the oxidation potential. The speed of polymerization also depended on the nature of the emulsion.The presence of egg albumen in the emulsion enhanced polymer formation with all oxidants. When the oxidants used are arranged in the order of decreasing speed of polymer formation, the order is different in the presence of albumen from what it is in the absence of albumen.With different oxidation catalysts most antioxidants and amino acids tested enhanced polymerization. In oxidation with ferric ions, with K‐dichromate, and without added oxidants the only antioxidants which delayed polymerization were “inhibitors”. “Retarders” enhanced polymerization. With KMnO4 slight delay was caused by some retarders.The findings indicate that not only oxidation catalysts, but also proteins, amino acids, and antioxidants enhance polymerization. The possibility is suggested that in animal cells lipid pigment formation might represent a mechanism for neutralizing free radicals.
Chemical Phenomena, Linolenic Acids, Ovalbumin, Polymers, Ascorbic Acid, Ferric Compounds, Antioxidants, Catalysis, Fluorescence, Peroxides, Chlorobenzoates, Chemistry, Kinetics, Potassium Permanganate, Potassium Dichromate, Amino Acids, Oxidation-Reduction
Chemical Phenomena, Linolenic Acids, Ovalbumin, Polymers, Ascorbic Acid, Ferric Compounds, Antioxidants, Catalysis, Fluorescence, Peroxides, Chlorobenzoates, Chemistry, Kinetics, Potassium Permanganate, Potassium Dichromate, Amino Acids, Oxidation-Reduction
| selected citations These citations are derived from selected sources. This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | 8 | |
| popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network. | Average | |
| influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | Average | |
| impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network. | Average |
