The polymorphism of diglycerides

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1992 English Publisher:WileyJournal:Journal of the Science of Food and Agriculture, volume 60, pages 405-417 (issn: 0022-5142, eissn: 1097-0010,

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Authors: R J Shannon; J. Fenerty; R J Hamilton; F B Padley;

doi: 10.1002/jsfa.2740600402

The polymorphism of diglycerides

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Abstract

AbstractThe polymorphism of 1,3‐dipalmitin, 1,2‐dipalmitoyl‐sn‐glycerol, 1.2‐dipalmitoyl‐rac‐glycerol has been examined by X‐ray diffraction, IR spectroscopy and Raman spectroscopy and differential scanning calorimetry. The respective spectra and thermographs are presented for these polymorphs. Optically active 1,2‐diglycerides exhibit very different thermal behaviour from the optically inactive 1,2‐diglycerides. A novel HPLC system was devised for the separation of the diglycerides.

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