Highly soluble perylene tetracarboxylic diimides (PDI)‐tetrathiafulvalene (TTF) dyad and TTF‐PDI‐TTF triad

descriptionPublicationkeyboard_double_arrow_right Article 01 Sep 2009 English Publisher:WileyJournal:Journal of Heterocyclic Chemistry, volume 46, pages 881-885 (issn: 0022-152X, eissn: 1943-5193,

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Authors: Chengyun Wang; Wei Tang; Hanbin Zhong; Xuechao Zhang; Yongjia Shen;

doi: 10.1002/jhet.160

Highly soluble perylene tetracarboxylic diimides (PDI)‐tetrathiafulvalene (TTF) dyad and TTF‐PDI‐TTF triad

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Abstract

Abstract magnified imageTwo highly soluble donor‐σ‐acceptor and donor‐σ‐accepter‐σ‐donor type fluorescence switches consisting tetrathiafulvalene (TTF) and 3,4,9,10‐perylene tetracarboxylic diimides (PDI) were synthesized. The structure of the dyad and triad as well as their intermediates was characterized by 1H NMR, 13C NMR MS, elemental analysis. Their fluorescence behavior could be modulated by oxidization and reduction of the TTF unit using either chemical or electrochemical method. J. Heterocyclic Chem., (2009).

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East China University of Science and Technology
China (People's Republic of)

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