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The Absolute Configuration of Dibromopalau'amine

descriptionPublicationkeyboard_double_arrow_right Article 12 Nov 2010 English Publisher:WileyJournal:European Journal of Organic Chemistry, volume 2,010, pages 6,900-6,903 (issn: 1434-193X, eissn: 1099-0690, Copyright policy )
Authors: Reinscheid, U.; Koeck, M.; Cychon, C.; Schmidts, V.; Thiele, C.; Griesinger, C. ; https://orcid.org/0000-0002-1266-4344;

doi: 10.1002/ejoc.201001392

handle: 11858/00-001M-0000-002A-901F-3 , 11858/00-001M-0000-0011-F1F1-2

The Absolute Configuration of Dibromopalau'amine

Abstract

AbstractWe determined the ensemble of conformations and therelative configuration of dibromopalau'amine by using NMR parameters such as 3J couplings, ROEs and residual dipolar couplings. Based on the ensemble electronic circular dichroism (ECD) and optical rotatory dispersion (ORD) spectra were calculated using DFT and compared to experiment. By this method the absolute configuration of natural (–)‐dibromopalau'amine was determined as 6S,10R,11S,12S,16R,17S,18S,20S.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
39
Top 10%
Top 10%
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