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Energy & Environmental Materials
Article . 2020 . Peer-reviewed
License: Wiley Online Library User Agreement
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ECS Meeting Abstracts
Article . 2020 . Peer-reviewed
License: IOP Copyright Policies
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Critical Factors Dictating Reversibility of the Zinc Metal Anode

Authors: Lin Ma; Marshall A. Schroeder; Travis P. Pollard; Oleg Borodin; Michael S. Ding; Ruimin Sun; Longsheng Cao; +4 Authors

Critical Factors Dictating Reversibility of the Zinc Metal Anode

Abstract

With high energy density and improved safety, rechargeable battery chemistries with a zinc (Zn) metal anode offer promising and sustainable alternatives to those based on lithium metal or lithium‐ion intercalation/alloying anode materials; however, the poor electrochemical reversibility of Zn plating/stripping, induced by parasitic reactions with both aqueous and non‐aqueous electrolytes, presently limits the practical appeal of these systems. Although recent efforts in rechargeable Zn metal batteries (RZMBs) have achieved certain advancements in Zn metal reversibility, as quantified by the Coulombic efficiency (CE), a standard protocol for CE has not been established, and results across chemistries and systems are often conflicting. More importantly, there is still an insufficient understanding regarding the critical factors dictating Zn reversibility. In this work, a rigorous, established protocol for determining CE of lithium metal anodes is transplanted to the Zn chemistry and is used for systematically examining how a series of factors including current collector chemistry, current density, temperature, and the upper voltage limit during stripping affect the measured reversibility of different Zn electrolytes. With support from density functional theory calculations, this standardized Zn CE protocol is then leveraged to identify an important correlation between electrolyte solvation strength toward Zn2+ and the measured Zn CE in the corresponding electrolyte, providing new guidance for future development and evaluation of Zn electrolytes.

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    158
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    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
158
Top 1%
Top 10%
Top 1%
bronze