Catalytic Deoxydehydration of Glycols with Alcohol Reductants

descriptionPublicationkeyboard_double_arrow_right Article 26 Mar 2013 English Publisher:WileyJournal:ChemSusChem, volume 6, pages 597-599 (issn: 1864-5631, eissn: 1864-564X,

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Authors: Camille, Boucher-Jacobs; Kenneth M, Nicholas;

doi: 10.1002/cssc.201200781

pmid: 23532937

Catalytic Deoxydehydration of Glycols with Alcohol Reductants

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Abstract

Top shelf dehydration: Ammonium perrhenate catalysts combined with benzylic alcohol reductants are used for the efficient deoxydehydration of glycols to olefins. The olefin and aldehyde products can be easily separated and isolated. It is also demonstrated that the catalyst can be recovered and reused because of its low solubility in aromatic solvents.

Related Organizations

University of Oklahoma
United States

Keywords

Glycols, Rhenium, Solvents, Alkenes, Oxidation-Reduction, Catalysis, Benzyl Alcohol

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